NOx selective catalytic reduction (SCR) on self-supported V–W-doped TiO2 nanofibers

Published in New Journal of Chemistry, vol. 41(9), pp. 3466–3472 (2017) · Royal Society of Chemistry
DOI: 10.1039/C6NJ03205B

Summary

Selective catalytic reduction (SCR) is the standard way to convert harmful nitrogen oxides (NOx) from exhaust and flue gases into harmless nitrogen, and the workhorse catalyst is vanadium–tungsten-doped titania. Conventionally this catalyst is coated onto a bulky honeycomb support. Here the authors instead electrospin V–W–TiO₂ directly into self-supporting, nonwoven ceramic nanofibres, in which vanadium and tungsten form a solid solution within the anatase TiO₂ phase. The interconnected, highly porous fibre mat lets every nanofibre act as a miniature reactor, so the membrane itself becomes an ultra-compact, lightweight SCR unit with open porosity and good mechanical integrity — no separate support needed. Preliminary catalytic tests indicate NOx conversion efficiency superior to a state-of-the-art reference material, demonstrating a promising route to compact de-NOx reactors.

Authors & Affiliations

Topics

NOx SCR Catalysis Ceramic Nanofibers Air Pollution Control Self-Supported Catalyst

Materials

Titanium Dioxide (TiO₂) Vanadium (V) Tungsten (W)

Linari Electrospinning Systems

Electrospinning machines by Linari Nanotech
Linari Nanotech designs and manufactures electrospinning systems for nanofiber research and production — including self-supported ceramic catalytic membranes.
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