Polybenzimidazole-Reinforced Terphenylene Anion Exchange Water Electrolysis Membranes

Published in ChemSusChem (2024) · Wiley · Open access, CC BY-NC-ND
DOI: 10.1002/cssc.202400825

Summary

Anion exchange membrane water electrolysis promises to combine the strengths of the two established routes to hydrogen - the performance of proton exchange membranes and the cheaper materials of alkaline systems. Getting there requires membranes with high hydroxide conductivity, low gas crossover and long service life, which are difficult to satisfy at once. This study reinforces terphenylene anion exchange membranes with electrospun polybenzimidazole, using a nanofibre mat to supply the dimensional stability the ionomer lacks.

Authors & Affiliations

  • Roberta Gentile
    ICGM, Université de Montpellier, CNRS, ENSCM, France
  • Sabrina C. Zignani
    CNR-ITAE, Istituto di Tecnologie Avanzate per l'Energia, Messina, Italy
  • Małgorzata Zatoń
    ICGM, Université de Montpellier, CNRS, ENSCM, France
  • Marc Dupont
    ICGM, Université de Montpellier, CNRS, ENSCM, France
  • François Lecœur
    ICGM, Université de Montpellier, CNRS, ENSCM, France
  • Nicolas Donzel
    ICGM, Université de Montpellier, CNRS, ENSCM, France

Linari Electrospinning Systems

Linari Engineering electrospinning system
The polybenzimidazole mats were spun on a Linari Engineering system at 20 kV, with a needle-to-collector distance of 10 cm and a flow rate of 0.4 ml/h. The paper does not name the model; see our range of electrospinning systems.

Topics

Water Electrolysis Green Hydrogen Anion Exchange Membranes Reinforced Membranes

Materials

Polybenzimidazole Terphenylene ionomers
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