Core/Double-Sheath Composite Fibers from Poly(ethylene oxide), Poly(L-lactide) and Beeswax

Published in Polymers, vol. 14(22), 5036 (2022) · MDPI · Open access, CC BY
DOI: 10.3390/polym14225036

Summary

Core-sheath fibres are normally made by coaxial electrospinning, with two solutions fed through concentric needles. This study takes a less common route: spinning a homogeneous blend of poly(ethylene oxide), poly(L-lactide) and beeswax from a single spinneret, and letting the components separate during spinning to form a core with a double sheath. The result is a layered architecture obtained without coaxial hardware, driven by the physical incompatibility of the three constituents rather than by the geometry of the needle.

Authors & Affiliations

  • Selin Kyuchyuk
    Laboratory of Bioactive Polymers, Institute of Polymers, Bulgarian Academy of Sciences, Sofia, Bulgaria
  • Dilyana Paneva
    Laboratory of Bioactive Polymers, Institute of Polymers, Bulgarian Academy of Sciences, Sofia, Bulgaria
  • Nevena Manolova Corresponding
    Laboratory of Bioactive Polymers, Institute of Polymers, Bulgarian Academy of Sciences, Sofia, Bulgaria
  • Iliya Rashkov
    Laboratory of Bioactive Polymers, Institute of Polymers, Bulgarian Academy of Sciences, Sofia, Bulgaria
  • Daniela Karashanova
    Institute of Optical Materials and Technologies, Bulgarian Academy of Sciences, Sofia, Bulgaria
  • Nadya Markova
    Institute of Microbiology, Bulgarian Academy of Sciences, Sofia, Bulgaria

Linari Electrospinning Systems

Linari high voltage generator (HVG-CONT-LCD)
The fibres were spun on Linari Engineering equipment (Pisa, Italy) at room temperature (22 °C) under controlled relative humidity - conditions worth recording precisely, since ambient humidity governs how the phases separate. Our high voltage control unit is coded HVG-CONT-LCD.

Topics

Core-Sheath Fibers Single-Spinneret Electrospinning Phase Separation Antibacterial Materials

Materials

Poly(ethylene oxide) Poly(L-lactide) Beeswax
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