Nanostructured, Metal-Free Electrodes for the Oxygen Reduction Reaction

Published in Molecules, vol. 27(6), 1832 (2022) · MDPI · Open access, CC BY
DOI: 10.3390/molecules27061832

Summary

Replacing platinum in the oxygen reduction reaction is one of the persistent goals of fuel cell research. This study combines three materials whose properties are complementary: nitrogen-doped carbon quantum dots, a hydroxide-conducting ionomer based on quaternised polysulfone, and polyaniline. The quantum dots were produced hydrothermally from glucosamine hydrochloride, alone or with N-octylamine, and the combination was assembled into nanostructured, metal-free electrodes for the oxygen reduction reaction in alkaline solution - a route to catalytic activity without precious metals.

Authors & Affiliations

  • Alaka R. Nallayagari
    CNRS, MADIREL, Aix Marseille University, France
  • Emanuela Sgreccia
    Department of Industrial Engineering, Tor Vergata University of Rome, Italy
  • Maria Luisa Di Vona
    Department of Industrial Engineering, Tor Vergata University of Rome, Italy
  • Luca Pasquini
    CNRS, MADIREL, Aix Marseille University, France
  • Florence Vacandio
    CNRS, MADIREL, Aix Marseille University, France
  • Philippe Knauth Corresponding
    CNRS, MADIREL, Aix Marseille University, France

Linari Electrospinning Systems

Electrospinning Starter Kit Random
The electrodes were prepared on a Linari Engineering Starter Kit Random setup, with a 10 ml syringe and a 0.8 mm needle mounted on the syringe pump at a controlled flow rate - the static-collector configuration described on our Starter Kit page.

Topics

Oxygen Reduction Reaction Metal-Free Electrodes Alkaline Fuel Cells Carbon Quantum Dots

Materials

N-doped carbon quantum dots Polysulfone Polyaniline
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