Versatile Production of Poly(Epsilon-Caprolactone) Fibers by Electrospinning Using Benign Solvents

Published in Nanomaterials, vol. 6(4), 75 (2016) · MDPI · Open access, CC BY
DOI: 10.3390/nano6040075

Summary

Electrospinning has long relied on solvents that are effective but toxic, and the shift towards benign alternatives usually comes at a cost: they demand far longer and more careful optimisation. This study demonstrates how versatile benign solvents can nonetheless be, using acetic acid and formic acid to produce poly(ε-caprolactone) fibres across a range of conditions. Establishing a workable process window for these solvents matters well beyond this one polymer, since it removes a recurring obstacle to using electrospun materials in biomedical settings.

Authors & Affiliations

  • Liliana Liverani Corresponding
    Institute of Biomaterials, University of Erlangen-Nuremberg, Germany
  • Aldo R. Boccaccini
    Institute of Biomaterials, University of Erlangen-Nuremberg, Germany

Linari Electrospinning Systems

Linari electrospinning system
The fibres were produced on a Linari Engineering S.r.l. system (Valpiana, Grosseto, Italy), with optimised parameters reported for each solution concentration - the kind of systematic mapping our complete stations are built for. Control unit HVG-CONT-LCD.

Topics

Benign Solvents Green Electrospinning Process Optimization Fiber Morphology

Materials

Poly(epsilon-caprolactone) Acetic acid Formic acid
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